Tavassoli, Milad, et al. International Journal of Biological Macromolecules 242 (2023): 125044.
This study explores the development of biodegradable pectin (PC)/chitosan nanofiber (ChNF) films infused with sumac anthocyanins for use in freshness monitoring and shelf-life extension of shrimp. The films' physical, barrier, morphological, color, and antibacterial properties were thoroughly evaluated. The incorporation of sumac anthocyanins led to intramolecular interactions, such as hydrogen bonding, confirmed by attenuated total reflectance Fourier transform infrared (ATR-FTIR) analysis, indicating good compatibility between the film components.
The smart films exhibited remarkable sensitivity to ammonia vapors, with a color change from reddish to olive within the first 5 minutes of exposure, signaling early spoilage. Furthermore, the films demonstrated significant antibacterial activity against both Gram-positive and Gram-negative bacteria. The PC/ChNF/sumac films maintained acceptable mechanical properties, with a tensile strength of 60 MPa and flexibility of 23.3%. The water vapor barrier also slightly improved, with a reduction in water vapor permeability from 2.5 × 10⁻¹¹ to 2.3 × 10⁻¹¹ g·m/m²·s·Pa after anthocyanin addition.
Applied to shrimp freshness monitoring, the films showed a clear color shift from reddish to greenish after 48 hours of storage, proving their potential as an effective, eco-friendly solution for real-time spoilage detection in seafood products. This work highlights the promising application of sumac anthocyanins in sustainable packaging and food safety technologies.